Preview

Eurasian Journal of Physics and Functional Materials

Advanced search

The effect of high-temperature annealing on the phase transformations of the perovskite YTiO3-x system

https://doi.org/10.29317/ejpfm.2019030308

Abstract

This paper presents the results of a study of the structural characteristics of perovskite systems based on YTiOx. These samples were subjected to heat treatment in the process of solid-phase synthesis. The change in physicochemical properties was investigated by scanning electron microscopy, X-ray structural and energy dispersive analysis. In the course of the work, it was found that the synthesized samples are a mixture of three phases characteristic of yttrium compounds with titanium. A quantitative change in the phases during the heat treatment indicates phase transformations and a change in the basic crystallographic characteristics. The results of these studies indicate that during thermal annealing, the density of perovskites changes, indicating phase transformations due to the mobility of impurity defects and distortion of the crystal lattice.

About the Authors

D. A. Mustakhieva
L.N. Gumilyov Eurasian National University
Kazakhstan


I. Z. Zhumataeva
L.N. Gumilyov Eurasian National University
Kazakhstan


A. L. Kozlovsky
Institute of Nuclear Physics of the Republic of Kazakhstan
Kazakhstan


K. K. Kadyrzhanov
L.N. Gumilyov Eurasian National University
Kazakhstan


References

1. J. Ault, A. Welch, Acta Crystallogr 20(3) (1966) 410.

2. K. Akihiro et al., Journal of the American Chemical Society 131(17) (2009) 6050.

3. J.K. Stalick, J.D. Jorgensen, Solid State Ionics 129(1-4) (2000) 111.

4. Y. Zhang, Ceramics International 40(4) (2014) 5223.

5. V.V. Lemanov, Kluwer Academic Publishers (2000) 329.

6. Z. Chen et al., Materials Letters 68 (2012) 137.

7. M. Arao, Y. Koyama, Physica C: Superconductivity 392-396 (2003) 300.

8. A.M. Glaser, Acta Crystallogr 28 (1972) 3384.

9. A.M. Glazer, Acta Crystallogr 31A(11) (1975) 3384.

10. A.M. Glazer, Acta Crystallogr 31A(6) (1975) 756.

11. J. Kitagawa et al., Journal of Magnetism and Magnetic Materials 310(2) (2007)913.

12. M. O’Keeffe, B.J. Hyde, Acta Crystallogr 33 (1977) 3802.

13. G.S. Pavitra et al., Phys. Status Solidi (RRL) Rapid Res 7(3) (2013) 224.

14. M.J. Reau et al., Mat. Res. Bull 13 (1978) 1415.

15. W. Menesklou, Sensors and Actuators B: Chemical 2-3(59) (1999) 184.

16. M. Ito et al., Journal of Physics and Chemistry of Solids 65(12) (2004) 1993.


Review

For citations:


Mustakhieva D.A., Zhumataeva I.Z., Kozlovsky A.L., Kadyrzhanov K.K. The effect of high-temperature annealing on the phase transformations of the perovskite YTiO3-x system. Eurasian Journal of Physics and Functional Materials. 2019;3(3):260-268. https://doi.org/10.29317/ejpfm.2019030308

Views: 367


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2522-9869 (Print)
ISSN 2616-8537 (Online)