A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
https://doi.org/10.29317/ejpfm.2018020309
Abstract
Cathode materials with mixed ion-electron conductivity (MIEC) are necessary for the development of low or intermediate temperature solid oxide fuel cells. Perovskite and perovskite-related materials are promising candidates on this role. In the review the conductivity and the thermal expansion of materials with various types of perovskite-related structures such as pure perovskite, double perovskite, brownmillerite and Ruddlesden-Popper phases have been compared. And the literature data on the values of the electronic and ionic conductivities, the oxygen diffusion coefficient, and the thermal expansion coefficient of various compositions have been collected. It was shown that the disordered cubic perovskites possess the higher electronic conductivity whereas the layered perovskites and materials with the Ruddlesden-Popper structure have higher ionic conductivity and lower value of thermal expansion.
About the Authors
A. V. Nikonov
Institute of Electrophysics Ural Branch Russian Academy of Sciences
Russian Federation
Russian Federation
K. A. Kuterbekov
L.N. Gumilyov Eurasian National University
Kazakhstan
Kazakhstan
K. Zh. Bekmyrza
L.N. Gumilyov Eurasian National University
Kazakhstan
Kazakhstan
N. B. Pavzderin
Institute of Electrophysics Ural Branch Russian Academy of Sciences
Russian Federation
Russian Federation
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Review
For citations:
Nikonov A.V., Kuterbekov K.A., Bekmyrza K.Zh., Pavzderin N.B. A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode. Eurasian Journal of Physics and Functional Materials. 2018;2(3):274-292. https://doi.org/10.29317/ejpfm.2018020309
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