Effect of lithium doping on electrophysical and diffusion properties of nonstoichiometric superionic copper selenide Cu1.75Se

Authors

M. Kh. Balapanov, Bashkir State University ,Russian Federation
K. A. Kuterbekov, L.N. Gumilyov Eurasian National University ,Kazakhstan
M. M. Kubenova, L.N. Gumilyov Eurasian National University ,Kazakhstan
R. Kh. Ishembetov, Bashkir State University ,Russian Federation
B. M. Akhmetgaliev, Bashkir State University ,Russian Federation
R. A. Yakshibaev, Bashkir State University ,Russian Federation ,

Abstract

The results of studies of the ionic conductivity and the conjugated chemical diffusion coefficients (CCDC) in the nonstoichiometric Li^xCu^1.75Se(0 ≤ x ≤ 0.25) ternary alloys are presented. It has been observed that the values of the ionic conductivity of Cu1.75Se copper selenide decreases with lithium doping in general owing to increasing the the activation energy. The increasing of the conjugate chemical diffusion coefficients of the cations and electron holes was observed with increasing of lithium content, despite the decreasing of self-diffusion coefficients of the cations and decreasing of electron mobilities. The behavior of the conjugate chemical diffusion coefficients explained by a decrease in the degree of non-stoichiometry of the composition, leading to an increase of the internal electric field accelerating the motion of slower particles.

Recommended Citation

Balapanov, M. Kh.; Kuterbekov, K. A.; Kubenova, M. M.; Ishembetov, R. Kh.; Akhmetgaliev, B. M.; and Yakshibaev, R. A. (2017) "Effect of lithium doping on electrophysical and diffusion properties of nonstoichiometric superionic copper selenide Cu1.75Se," Eurasian Journal of Physics and Functional Materials: Vol. 1: No. 2, Article 3.
DOI: 10.29317/ejpfm.2017010203
Available at: https://www.ephys.kz/journal/vol1/iss2/3

First Page

40

Last Page

49

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