•  
  •  
 

Abstract

The paper presents experimental results of concentration polarization and ionic conductivity of nanocom- posite thermoelectric materials K0.01Cu1.94S , K0.02Cu1.94S , K0.03Cu1.94S . According to X-ray phase analysis, the synthesized samples are monoclinic jarleite Cu1.93÷1.97S with an admixture of oxygen ox- ide Cu2S and monoclinic chalcocyte. High values of total ionic conductivity are observed, ranging from 0.86 to 1.5 Cm/cm. The lowest ionic conductivity (0.86 Cm/cm at 355 ◦ C) is observed for alloy K0.02Cu1.94S . In addition, it was found that with an increase in the concentration of potassium in the studied materials, ionic conductivity tends to decrease, activation energy increases, but the characteris- tics of ion transport remain high, corresponding to superionic materials

Article Type

Original Study

First Page

45

Last Page

51

Creative Commons License

Creative Commons Attribution 4.0 International License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Share

COinS